Hi there.
Firstly, you cannot test the output of an ignition coil by measuring it's output voltage with a meter because it is in the region of tens of thousands of volts. One tests in two ways. One is to get a spare spark plug, connect to to any of the 4 spark plug leads, hold the body of the plug onto a clean bit of alloy on the engine and get an assistant to try and start the engine. One looks at the plug tip and you should see a spark. The whiter the spark the better, though they always have a blue tint.
IMPORTANT = You
have to do this VERY carefully as if you get it wrong you can get a nasty, even dangerous electric shock (thousands of Volts). I usually earth the body of the plug by holding it with a very dry towel or similar and make sure it is held firmly against that (good) earth on the motor.
Secondly, you can test the windings inside the coil are in good nick by measuring their resistance with your meter. Details on how to do that are in our wiki here ->
https://club8090.co.uk/wiki/VW ... ition_Coil" onclick="window.open(this.href);return false;
However, and here I have to admit that my knowledge on "our" ignition systems has let me down, I could research it, but someone will be along soon to clarify. Your symptoms are those of a cold start voltage boost circuit fault, known as a "ballast circuit", but I am not sure if our vans use this system. Many vehicles of our vintage did, but I think mainly on the more basic points style ignition systems, not on electronic ignition systems like ours.
The following in small type because it is purely information only and as said, might be irrelevant on our vans) =
A "ballast system" coil actually runs off 8 Volts normally, it only gets 12 Volts whilst actually starting the engine (to boost the spark). Once the engine is running a resistor drops the voltage to 8 Volts. So, if the resistor or it's wiring is faulty, the motor won't receive sparks whilst cranking, but for that 1/2 second after you cease cranking it will. This causes the symptoms of not "catching" whilst cranking, but sometimes succeeding in "catching" as you release the key. Someone will be along soon re this "ballast" or "no ballast" thing

(I'm now thinking we don't have it

)
So, test your coils resistance as per wiki.
Carefully test for an actual spark. Or, if you have a friendly T25 owner nearby, you could test the coil via substitution.
If it turns out not to be the coil, the next, and quite common thing to fail is the ignition amp. A little black box on the bulkhead, just forward of the coil, about the size of a fag packet. Testing for a problem there is best done by substitution with a known good one. I always carry a spare one of these.
Let us know if you can find a good spark.