I use the Carlube SemiSynthetic 75W/90 GL4/GL5 when rebuilding the boxes and in mine front and rear, recommend changing every 2-3 years max on a syncro, more often if worked hard - the Carlube appears to be the same as the Fuchs I used before and as close to the original spec as possible, may even be the same/equivilent modern version of
as long as it says GL4 that's good, if it only says GL5 then avoid except front diff that's ok as no brass syncro rings to worry about
I do not recommend MT90 or any of the higher spec synthetic oils they don't seem to offer enough protection to crown and pinion and big drive gears, rather put in mineral GL4 than them
Additives it's a matter of choice, I probably should put them in every box but it feels almost like an admission of failure, even though I think VW used them originally, but no real evidence of that - I'm running the Wurth additive in mine this oil change - I was given a sample to try, tell you in 2 years what I think
