It had this exact problem before and after the engine swap, and the van shows signs of people chasing "hot" issues in the past (cooling fan bodged on a manual switch etc)
it's had a new radiator/waterpump/stat/temp sensor and has been bled up and worked on by ex-vw mechanics who worked on these when they were current.
Symptoms are that it would idle happily all day - fan cuts in and out etc, temp needle is 2/3rds on the gauge so a bit hot but not horrific. Temp sender resistance after 90minutes idling was 85-90 ohms, so ~100c coolant temp.
Within 2 miles of driving (even from stone cold) the needle is off the top of the scale and soon after this, the warning light flashes, but he's driven it for weeks like this

I've bench tested his clocks and they are fine and read exactly the same needle position as the 3 other sets I have here (120 ohms is 50%), and I've checked his vehicle wiring and replaced earths etc. The temp sensor is new. Coolant level relay (43) in or out makes no difference.
The only thing I haven't managed to do is completely isolate the temp sensor and measure the resistance when it's driving to be 100% sure that it's reading very very hot water.
My suspicion is a blocked (it still has the original plastic pipes and I suspect one of the steel inserts is working it's way round the system) or maybe a misrouted cooling hose.
Any ideas?