Voltage at the alternator output with no load (except the ignition circuit) = 14.1 Volts (new(ish) 14 Volt regulator/brush pack)
Voltage at the starter battery (under same load conditions) = 13.8 Volts.
Voltage into the split charge relay = 13.7 Volts.
Voltage out of the split charge relay = 13.6 Volts.
Voltage at the leisure battery = 13.3 Volts

Now I have double checked the condition of the main feed from the alternator, the condition of the wire (none of the "black wire" corrosion CovKid mentions) all is clean and bright. The terminals on the solenoid are equally clean and bright (it was a new starter assembly only 3 or 4 years ago).
The terminals on both batteries are clean and bright. Both batteries are less than a year old and hold a charge with no problem. Both read 12.9 Volts after a rest. The wire from the starter +ve to the relay and from the relay to the leisure is military spec (ex BR actually

As I say, no real problem here, it just shows how every bit of wire and every connection degrades the performance of the circuit (this is well known in Amateur radio circles regarding aerial connectors).
In fact, by the time you get to the fuse box, I am reading only 12.9 Volts


I think I will fit a separate feed from the alternator to the split charge relay, and maybe fit a better relay too, to re-gain some of that valuable charging current to the leisure battery !
Comments invited...