You would not need a 12 Volt regulator to protect anything on the vehicle from 14.4 Volts. Everything on our vans is just fine at 14.4 Volts (even car stereos and alarms etc are fine up to 16 Volts)
I was thinking of running a cable from the alternator regulators sense wire all the way to the starter battery so the alternator would regulate to the battery voltage terminals and not just the alternator output.
In almost every vehicle setup the sense wire of the regulator is connected directly to the alternator output which regulates the output voltage directly at the alternator. In most vehicles this isn’t a problem as the battery is right next to the alternator so the cable losses aren’t an issue, but in our vans the battery is miles away so although you might get a nice regulated 14.4V at on the alternator terminals this is significantly reduced when it gets to the battery due to the losses in the cables.
If you connect the sense wire to the battery terminals then the regulator will adjust the output of the alternator so you get 14.4V at the battery terminals regardless of the cable loss. As an extreme example, if the total cable losses from the alternator to the battery were 2V then the voltage at the alternator terminals would be 16.4V and the battery voltage would stay at 14.4V.
With this setup you would get a battery that would always charged pretty quickly (you’d probably actually use a regulator set to 14V to avoid overheating the battery) but you’d have everything on the alternator side of the batter, which is all the engine electrics, connected to a voltage supply that would be going up and down depending on how much the voltage drop on the cable from the alternator to the battery was, which is why you’d need a 12V regulator for the engine electrics.
Another issue would be that you’d have to occasionally check condition of the cabling as any problems with the cabling wouldn’t be apparent at the battery as the alternator would be compensating for it and could in the end overheat the whole cable.
Just a thought anyway

On the subject of DC current measurement, you can pick up a DC clamp meter on Amazon for about £20 that would measure the charging current without mucking about with Shunts or putting anything in series with cabling. Would make things like this a lot easier

On a side note, if you remove the alternators diode block and do some mucking about with the sense wire you can get alternators to produce about 220V AC, but the frequency is obviously all over the place as it’s proportional to the engines speed…