So, two 2400 x 1200 sheets of 25mm rigid foam board faced in glassfibre tissue and a sheet of 12mm exterior ply cut into 100mm wide strips. I had to cut down the boards down to get them to fit into the van to get them home. This wasn't really a problem since the widest board I could find was 1200mm and the roof needs to be 1400mm wide - so there would have to be a join somewhere anyway...

Pound shop sanding blocks, Lidl 'two for £3' breadknife and an old small sharp bladed knife for more intricate cutting!

I found a whole community of 'foamy' mini campers online and their favoured joining method seemed to be Gorilla Glue. I've never used this stuff before, but it seems to turn into some sort of sticky expanding foam when it comes into contact with water. My first attempt was the join down the middle of the roof. This seems to have joined OK, but the glue certainly expands as it cures. It may have been an idea to use tape along the length of the join to keep things a bit smoother, but the excess trimmed off OK. The entire roof will be encased in GRP/ epoxy so I'm not too concerned about the finish at this stage.
I've now got the side panels cut to shape too and have left the roof with the ply stuck down along the outside edges and across the roof at the skylight hole. I've had to come in to work this evening, so will get a picture of this framing in the morning - hopefully all bonded together nicely!